Violence erupted for a seventh night across several parts of the US, just hours after President Donald Trump vowed to use military personnel to halt the protests.
"Mayors and governors must establish an overwhelming law enforcement presence until the violence has been quelled," Trump said.
"If a city or state refuses to take the actions that are necessary to defend the life and property of their residents, then I will deploy the United States military and quickly solve the problem for them."
Following his address, he walked from the White House to nearby St. John's Episcopal Church amid tight security to pose for pictures with his daughter Ivanka.
However, a few hours later, thousands of people marched through the streets of Brooklyn, shouting "justice now!", while demonstrators in Los Angeles and New York City clashed with riot police.
George Floyd, a 46-year-old African-American, was killed minutes after a policeman pinned his neck under a knee for nearly nine minutes.
A Russian missile struck a hotel in the central Ukrainian city of Kryvyi Rih late on Wednesday, killing four people and injuring 31, with rescuers still searching on Thursday morning for anyone trapped in the rubble, officials said.
The United States broke a long-standing diplomatic taboo by holding secret talks with Hamas on securing the release of US hostages held in Gaza, sources told Reuters on Wednesday, while US President Donald Trump warned of "hell to pay" should the Palestinian group not comply.
The US has paused intelligence sharing with Ukraine, CIA Director John Ratcliffe said on Wednesday, piling pressure on Ukrainian President Volodymyr Zelenskyy to cooperate with US President Donald Trump in convening peace talks with Russia.
New footage shows the moment Firefly Aerospace's Blue Ghost has became the first ever successful commercial moon landing, following touchdown on Mare Crisium, a basin in the north-east quadrant of the Moon.